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Which of the following linear chain alcohols is likely to have the largest standard molar entropy in the liquid state?


A) CH3OH
B) CH3CH2OH
C) CH3CH2CH2OH
D) CH3CH2CH2CH2OH
E) CH3CH2CH2CH2CH2OH

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The second law of thermodynamics states that


A) in a spontaneous process,there is a net increase in entropy,taking into account both the system and the surroundings.
B) there is no disorder in a perfect crystal at 0 K.
C) the total energy of the universe is always increasing.
D) the total energy of the universe is constant.
E) mass and energy are conserved in all chemical reactions.

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All of the following statements are true EXCEPT


A) a reaction is spontaneous if ΔG < 0.
B) if ΔG = 0,the system is at equilibrium.
C) if ΔG = 0,then ΔS = ΔH.
D) if ΔG > 0,then a reaction is not spontaneous.
E) ΔG is referred to as Gibbs free energy.

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All of the following statements are true EXCEPT


A) for a given material,the gas has greater entropy than the solid.
B) the entropy for gaseous elements is zero at 298 K.
C) at 0 K,an ordered pure crystalline solid has an entropy of zero.
D) for a given material,the liquid has greater entropy than the solid.
E) increasing the temperature of a substance increases its entropy.

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For a chemical reaction,ΔG and ΔG° are equal


A) when products and reactants are in standard state concentrations.
B) when K = 0.
C) when K > 1.
D) for a system at equilibrium.
E) when the entropy change is zero.

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Predict the sign of ΔS and ΔH for the combustion of gasoline at 500 K.


A) ΔH > 0 and ΔS > 0
B) ΔH > 0 and ΔS = 0
C) ΔH < 0 and ΔS > 0
D) ΔH < 0 and ΔS < 0
E) ΔH < 0 and ΔS = 0

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All of the following statements are false for the freezing of water at 273 K EXCEPT


A) ΔH < 0.
B) ΔH > 0.
C) ΔH = 0.
D) ΔS = 0.
E) ΔS > 0.

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Nitric oxide can be made from the reaction of oxygen and nitrogen gases. O2(g) + N2(g) → 2NO(g) If ΔG° = 165.5 kJ,and ΔH° = 180.4 kJ,what is ΔS° at 325°C?


A) 0.0125 kJ/K
B) 0.0249 kJ/K
C) 0.0458 kJ/K
D) 0.142 kJ/K
E) 1.02 kJ/K

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When ammonium nitrate dissolves spontaneously in water the temperature of the solution decreases.Which statement is true for this system?


A) ΔH < 0 and ΔS < 0
B) ΔH < 0 and ΔS = 0
C) ΔH = 0 and ΔS > 0
D) ΔH > 0 and ΔS > 0
E) ΔH > 0 and ΔS < 0

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