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Which of the following double bonds do you predict to be the shortest based on the position of the atoms in the periodic table?


A) C=O \mathrm{C}=\mathrm{O}
B) N=O \mathrm{N}=\mathrm{O}
C) S=O \mathrm{S}=\mathrm{O}
D) N=N \mathrm{N}=\mathrm{N}

E) None of the above
F) C) and D)

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Which of the following molecules contains an exception to the octet rule?


A) NO
B) CO
C) HBr
D) I2
E) N2O

F) C) and E)
G) C) and D)

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Which statement about the most stable Lewis structures of cyanamide (H2NCN) and its structural isomer (HNCNH) is not correct?


A) Both have 16 valence electrons.
B) One has a triple bond.
C) One has two double bonds.
D) All atoms in both structures have formal charges of zero.
E) Cyanamide has an equivalent resonance structure with two double bonds.

F) C) and D)
G) C) and E)

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In which of the following molecules does the central atom have an expanded octet?


A) N2O
B) PCl5
C) BeF2
D) AsF3
E) NO2

F) D) and E)
G) A) and B)

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The complete combustion of carbon compounds produces carbon dioxide. The reaction of coal with water at high temperatures produces synthesis gas, which is a mixture of carbon monoxide and hydrogen. Use the bond energies in the table below to estimate how much more energy is released by reaction I than by reaction II; that is, estimate Δ\Delta HI - Δ\Delta HII. (I) C(g) + O2(g) \rightarrow CO2(g) (II) C(g) + H2O(g) \rightarrow CO(g) + H2(g)  Bond OCCOHHH==OOO Energy (kJ/mol) 4957701,070465435\begin{array} { | l | c | c | c | c | c | } \hline \text { Bond } & \mathrm { O } & \mathrm { C } & \mathrm { C } & \mathrm { O } - \mathrm { H } & \mathrm { H } - \mathrm { H } \\& = & = & \equiv & & \\& \mathrm { O } & \mathrm { O } & \mathrm { O } & & \\\hline \text { Energy } ( \mathrm { kJ } / \mathrm { mol } ) & 495 & 770 & 1,070 & 465 & 435 \\\hline\end{array}


A) 470 kJ/mol
B) 770 kJ/mol
C) 275 kJ/mol
D) 575 kJ/mol
E) 1,045 kJ/mol

F) None of the above
G) B) and D)

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Hydrogen isocyanide (HNC) and hydrogen cyanide (HCN) have the same elemental composition. Is one structure more stable than the other? Support your answer with the Lewis structures and formal charges assigned to each atom for these molecules.

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blured image The formal charges are zero u...

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Which sequence does not have the elements arranged correctly in order of increasing electronegativity?


A) I < Br < Cl
B) B < N < O
C) H < C < N
D) H < Li < S
E) Al < S < Cl

F) D) and E)
G) None of the above

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Which of the following ions does not have a complete valence-shell octet?


A) Al3+
B) I-
C) Ca2+
D) Pb2+
E) S2-

F) A) and E)
G) D) and E)

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In a chemical reaction, bonds are broken and new bonds are formed. Which one of the following statements regarding bond energies is correct?


A) Energy is released when bonds are broken.
B) Energy is released when bonds are broken and more stable bonds are formed.
C) Energy is released when bonds are broken and less stable bonds are formed.
D) Bond energies and bond lengths generally are not correlated; that is, they vary independently.
E) Bond energies and bond order are unrelated to each other.

F) B) and D)
G) A) and B)

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Which of the following bonds is least polar?


A) H--O
B) H--N
C) H--B
D) H--C
E) H--F

F) A) and E)
G) A) and C)

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When sulfur-containing fuels are burned, sulfur trioxide (SO3) is formed in the atmosphere and contributes to acid rain (sulfur trioxide plus water produces sulfuric acid) . How many resonance structures are there for SO3 when each atom satisfies the octet rule?


A) 0
B) 1
C) 2
D) 3
E) 4

F) B) and D)
G) All of the above

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Which of the following atoms can have an expanded octet?


A) S
B) C
C) N
D) B
E) Be

F) B) and E)
G) C) and E)

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Indicate the ion that does not have 8 valence electrons.


A) O-
B) Na+
C) Al3+
D) P3-
E) Ar

F) A) and E)
G) None of the above

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Using the positions of the atoms in the periodic table, identify which of the following bonds is expected to be most polar: C__F, Cl__F, Si__F, S__F, O__F.

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Which of the following molecules cannot absorb infrared radiation?


A) HCl
B) CH4
C) N2
D) C6H6
E) CO

F) A) and E)
G) B) and C)

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Which of the following represents the best Lewis structure for dinitrogen sulfide?


A) Which of the following represents the best Lewis structure for dinitrogen sulfide? A)    B)    C)    D)    E)
B) Which of the following represents the best Lewis structure for dinitrogen sulfide? A)    B)    C)    D)    E)
C) Which of the following represents the best Lewis structure for dinitrogen sulfide? A)    B)    C)    D)    E)
D) Which of the following represents the best Lewis structure for dinitrogen sulfide? A)    B)    C)    D)    E)
E) Which of the following represents the best Lewis structure for dinitrogen sulfide? A)    B)    C)    D)    E)

F) B) and C)
G) C) and D)

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Indicate which one of the following does not contain a polar covalent bond.


A) I2
B) CO
C) HF
D) NO
E) CN-

F) A) and E)
G) C) and E)

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How many covalent bonds are there in CN-?


A) 1
B) 2
C) 3
D) 0
E) 4

F) A) and E)
G) B) and D)

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How many valence electrons are there in BrO-?


A) 7
B) 6
C) 13
D) 14
E) 18

F) D) and E)
G) A) and B)

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How many lone-pair electrons are on the central atom of xenon tetrachloride? (XeCl4) ?


A) 2
B) 4
C) 8
D) 10
E) 6

F) C) and D)
G) B) and C)

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