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Understand some of the properties of equilibrium constants.

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Concentrations or partial pres...

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Write the equilibrium constant expressions for the following reaction: N2(g) + 3 H2(g) Write the equilibrium constant expressions for the following reaction: N<sub>2</sub>(g) + 3 H<sub>2</sub>(g)   2 NH<sub>3</sub>(g) 2 NH3(g)

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based on p...

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A system in chemical equilibrium is characterized by one of the following:


A) molecules no longer undergo reactions of any kinds.
B) macroscopic changes are observed.
C) unaffected by changes in temperature.
D) unaffected by addition of catalyst.
E) concentrations are changing at a fixed constant rate.

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Relate the equilibrium position to thermodynamic quantities.

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Reactions always mov...

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Solve quantitative equilibrium problems.

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If initial concentrations and ...

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Draw a graph of concentration vs. time for a system containing cis- and trans-butene in equilibrium (assume the equilibrium constant is 3.0) to which is added an amount of trans-butene equal to that present in the original mixture and monitored until equilibrium is reached again.

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Addition of sodium mono-hydrogencarbonate to water gives what major species?


A) H2O; H+; CO32-
B) H+, CO32-, OH-; H2CO3
C) NaHCO3
D) H2O; Na+; H2CO3, OH-
E) H2O; Na+; HCO3-

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Determine the equilibrium constant at 0oC for the following unbalanced reaction:Ba(OH)2.08H2O(s) + NH4NO3(s) \rightarrow Ba(NO3)2(s) + H2O(l) + NH3(aq)  Determine the equilibrium constant at 0<sup>o</sup>C for the following unbalanced reaction:Ba(OH)<sub>2</sub>.08H<sub>2</sub>O<sub>(s)</sub> + NH<sub>4</sub>NO<sub>3(s)</sub>  \rightarrow Ba(NO<sub>3</sub>)<sub>2(s)</sub><sub> </sub>+ H<sub>2</sub>O<sub>(l)</sub> + NH<sub>3(</sub><sub>aq</sub><sub>)</sub>

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Challenging multi-step problem requiring...

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At 1033ºK, K = 33.3 M for the equilibrium reaction:PCl5 (g) At 1033ºK, K = 33.3 M for the equilibrium reaction:PCl<sub>5</sub><sub> </sub><sub>(</sub><sub>g</sub><sub>)</sub>   PCl<sub>3</sub><sub> </sub><sub>(</sub><sub>g</sub><sub>)</sub> + Cl<sub>2</sub><sub> </sub><sub>(</sub><sub>g</sub><sub>)</sub>If a mixture of 0.100 mole of PCl<sub>5</sub> and 0.300 mole of PCl<sub>3</sub><sub> </sub>is placed in a 2.00 L reaction vessel and heated to 1033ºK, what are the numbers of mols of each component at equilibrium? PCl3 (g) + Cl2 (g)If a mixture of 0.100 mole of PCl5 and 0.300 mole of PCl3 is placed in a 2.00 L reaction vessel and heated to 1033ºK, what are the numbers of mols of each component at equilibrium?

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mols of PCl5 = 1.18 x ...

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Calculate the equilibrium constant for the oxychlorination of ethylene to vinyl chloride, CH2CHCl, under standard conditions at 100oC given the thermodynamic data below collected at 25oC: Δ\Delta G° = 53.6(CH2CHCl), -95.3(HCl), 68.49(CH2CH2), -228.7(H2O) kJ/mol Δ\Delta H° = 37.2(CH2CHCl), -92.3(HCl), 52.4(CH2CH2), -241.8(H2O) kJ/mol The equation of reaction is: CH2CH2 (g) + HCl (g) + 12\frac{1}{2} O2 (g) \rarr CH2CHCl (g) + H2O (g)

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1.56 x10

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Write the equilibrium constant expression for the following reaction: 2 N2 (g) + 2O2 (g) Write the equilibrium constant expression for the following reaction: 2 N<sub>2 </sub>(g) + 2O<sub>2 </sub>(g)   4 NO (g) 4 NO (g)

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based on p...

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If the dissolution of CaCl2 is endothermic, will any of the following increase the amount of CaCl2 that will dissolve in water?


A) addition of NaCl
B) addition of Ca(NO3) 2
C) addition of HCl
D) increase in temperature
E) decrease in temperature

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Write the equilibrium constant expressions and state the reference concentrations for the reactants and products: Cl2 (g) + 2 H2O (l ) Write the equilibrium constant expressions and state the reference concentrations for the reactants and products: Cl<sub>2</sub><sub> </sub>(g) + 2 H<sub>2</sub>O (l )   HOCl<sup> </sup>(aq) + Cl<sup>- </sup>(aq) + H<sub>3</sub>O<sup>+</sup> (aq) HOCl (aq) + Cl- (aq) + H3O+ (aq)

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Addition of sodium mono-hydrogencarbonate to water gives what minor species?


A) H2O; Na+; H+; CO32-
B) H2O; Na+; OH-; H2CO3
C) H2O; NaHCO3
D) H2O; Na+; H3CO3+; OH-
E) H2O; Na+; HCO3-

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Calcite, CaCO3(s), can be converted to CaO(s) and CO2(g). What is the equilibrium pressure of CO2 at 1150ºK? Calcite, CaCO<sub>3(</sub><sub>s</sub><sub>)</sub>, can be converted to CaO<sub>(</sub><sub>s</sub><sub>)</sub> and CO<sub>2(</sub><sub>g</sub><sub>)</sub>. What is the equilibrium pressure of CO<sub>2</sub> at 1150ºK?

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Challenging multi-step problem requiring...

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The conversion of nitrogen and hydrogen to ammonia is an important industrial reaction:N2 (g) + 3 H2 (g) The conversion of nitrogen and hydrogen to ammonia is an important industrial reaction:N<sub>2</sub> <sub>(</sub><sub>g</sub><sub>)</sub> + 3 H<sub>2</sub> <sub>(</sub><sub>g</sub><sub>)</sub>   2 NH<sub>3</sub> <sub>(</sub><sub>g</sub><sub>)</sub>If a tank initially containing only nitrogen at 1.0 atm and hydrogen at 3.0 atm converts 13.0 % of the nitrogen to ammonia, what is the value of the equilibrium constant for the reaction at this temperature? 2 NH3 (g)If a tank initially containing only nitrogen at 1.0 atm and hydrogen at 3.0 atm converts 13.0 % of the nitrogen to ammonia, what is the value of the equilibrium constant for the reaction at this temperature?

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When ammonia dissolves in water the new major species present are


A) H2O; NH2-; H+
B) H2O; NH3
C) H2O; NH4+; OH-
D) H2O; NH2-; H+
E) H2O; N3-; H+

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Adding water to the reaction vessel in which the following reaction is occurring will result inBa(OH) 2.8H2O(s) + NH4NO3(s) \rarr Ba(NO3) 2(s) + H2O(l) + NH3(aq)


A) no change.
B) reaction will shift right as the concentration of NH3 is decreased.
C) reaction will shift to the left as more product is added.
D) reaction will shift to the right as more product is added.
E) reaction will shift left as the concentration of NH3 is increased.

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When is a reaction at equilibrium?


A) when K = 1
B) when all concentrations are equal
C) when Q = 1
D) when all concentrations are equal to 1 M or 1 atm
E) when Q = K

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A sample of 3.00 x 10-1 mole of pure phosgene gas, COCl2, was placed in a 15.0 L container and heated to 800ºK. At equilibrium, the partial pressure of CO was found to be 0.497 bar. Calculate the equilibrium constant for the following reaction:COCl2 (g) A sample of 3.00 x 10<sup>-1</sup><sup> </sup>mole of pure phosgene gas, COCl<sub>2</sub>, was placed in a 15.0 L container and heated to 800ºK. At equilibrium, the partial pressure of CO was found to be 0.497 bar. Calculate the equilibrium constant for the following reaction:COCl<sub>2</sub><sub> </sub><sub>(</sub><sub>g</sub><sub>)</sub>   CO <sub>(</sub><sub>g</sub><sub>)</sub> + Cl<sub>2</sub><sub> </sub><sub>(</sub><sub>g</sub><sub>)</sub> CO (g) + Cl2 (g)

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