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Exam 8: Alcohols, Phenols, Ethers, and Their Sulfur Analogs

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Question 21

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Instructions: Consider the Grignard reaction below to answer the following question(s). Refer to instructions. The nucleophile in this reaction is indicated by letter _____.

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verified

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Question 22

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Instructions: Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. Write the product(s):

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Question 23

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Instructions: Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. Write the product(s):

Instructions: Draw structures corresponding to each of the following IUPAC names. Draw: 2, 4, 6-trinitrophenol

Instructions: Consider the reaction below to answer the following question. Refer to instructions. On the structures provided below draw arrows showing the mechanism of step two of this reaction.

What is the IUPAC name of the following compound?

Instructions: Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. Write the product(s):

Instructions: Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. Write the product(s):

What is the best way to make the following ether by a Williamson ether synthesis?

Instructions: Choose the best reagent(s) for carrying out the following conversions from the list provided below. Place the letter of the best choice in the blank. Reagents may be used more than once. $a.~~~~~ \mathrm{CrO}_{3}, \mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{H}_{2} \mathrm{O}$ $b.~~~~~$ 1. $\mathrm{NaBH}_{4}$ , ethanol $~~~~~~~~$ 2. $\mathrm{H}_{3} \mathrm{O}$ $c.~~~~~$ 1. $\mathrm{LiA1}_{4}$ , ether $~~~~~~~~$ 2. $\mathrm{H}_{3} \mathrm{O}^{+}$ $d.~~~~~~$ periodinane Refer to instructions: ______

Instructions: Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. Write the product(s):

Instructions: Give the major organic product(s) of the following reactions or sequences of reactions. Show all relevant stereochemistry. Write the product(s):

Which of the following would not react with either Na₂Cr₂O₇ or periodinane?

Instructions: Consider the Grignard reaction below to answer the following question(s) . Refer to instructions. If a secondary alcohol were desired as a product of the reaction, B should be replaced with

Instructions: Draw structures corresponding to each of the following IUPAC names. Draw: 3-methylbutane-1-thiol

What is the IUPAC name of the following compound?

What is the IUPAC name of the following compound?

Instructions: Consider the Grignard reaction below to answer the following question(s). Refer to instructions. The electrophile in this reaction is indicated by letter _____.

Instructions: Draw structures corresponding to each of the following IUPAC names. Draw: 3-methylbut-2-en-1-ol