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If (S) -glyceraldehyde has a specific rotation of -8.7°, what is the specific rotation of (R) -glyceraldehyde?


A) 0.0°
B) -8.7°
C) +8.7°
D) cannot be determined from the information given

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What term describes the structural relationship between (2R,3R,4S) -2,3,4-trichloroheptane and (2S,3S,4R) -2,3,4-trichloroheptane?


A) not isomers
B) constitutional isomers
C) enantiomers
D) diastereomers
E) conformers

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Draw the Fischer projection of (2R,4R)-2,4-dibromopentane.

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Draw the structure of (2R,3S)-2,3-dichloropentane. Take particular care to indicate three-dimensional stereochemical detail properly.

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Which of the following  incorrectly \underline{\text{ incorrectly }} describes  cis \underline{\text{ cis }} -1,2-dimethylcyclopentane?


A) It is a meso compound.
B) It is achiral.
C) It contains two asymmetric carbons.
D) Its diastereomer is trans \underline{\text{trans }} -1,2-dimethylcyclopentane.
E) It has an enantiomer.

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How many asymmetric carbon atoms are present in the molecule shown? How many asymmetric carbon atoms are present in the molecule shown?   A)  0 B)  1 C)  2 D)  3 E)  4


A) 0
B) 1
C) 2
D) 3
E) 4

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Which of the following statements correctly pertains to a pair of enantiomers?


A) They rotate the plane of polarized light by exactly the same amount and in opposite directions.
B) They rotate the plane of polarized light by differing amounts and in opposite directions.
C) They rotate the plane of polarized light by differing amounts and in the same direction.
D) The have different melting points.
E) They have the same melting point, but they have different boiling points.

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What term describes the structural relationship between (E) - and (Z) -2-pentene?


A) not isomers
B) constitutional isomers
C) enantiomers
D) diastereomers
E) conformers

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Provide a Fischer projection of (2S,3S,4S)-2,3,4-trichloroheptane.

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Draw the structure of the meso form of 1,3-dichlorocyclopentane. Take particular care to indicate three-dimensional stereochemical detail properly.

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Use the following three structures to answer the questions below. Use the following three structures to answer the questions below.   -The relationship between I and II is: ________. A)  same compound B)  enantiomers C)  diastereomers D)  constitutional isomers -The relationship between I and II is: ________.


A) same compound
B) enantiomers
C) diastereomers
D) constitutional isomers

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Is the molecule shown below chiral or achiral? Is the molecule shown below chiral or achiral?

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Label each asymmetric carbon in the compound below as R or S. Label each asymmetric carbon in the compound below as R or S.

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If a mixture contains 75% of one compound and 25% of its enantiomer, what is the e.e. of the mixture?


A) 100
B) 75
C) 50
D) 25
E) 3

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Label each asymmetric carbon in the compound below as R or S. Label each asymmetric carbon in the compound below as R or S.

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If possible, draw the structure of the enantiomer of the molecule shown below. If possible, draw the structure of the enantiomer of the molecule shown below.

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A newly isolated natural product was shown to be optically active. If a solution of 2.0 g in 10 mL of ethanol in a 50 cm tube gives a rotation of +2.57°, what is the specific rotation of this natural product?

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Draw the structure of (1R, 2R)-1-bromo-2-chlorocyclobutane. Take particular care to indicate stereochemistry properly.

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Label each asymmetric carbon in the compound below as R or S. Label each asymmetric carbon in the compound below as R or S.

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Which of the following terms best describes the pair of compounds shown:  enantiomers, diastereomers \underline{\text{ enantiomers, diastereomers }} , or  the same compound? \underline{\text{ the same compound? }}  Which of the following terms best describes the pair of compounds shown:  \underline{\text{  enantiomers, diastereomers }}  , or  \underline{\text{ the same compound?  }}

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